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1、UvinulTS HydroThe UVA Filter in WaterOctober 2421Insights on the Water Soluble UVA-Filter2UvinulTS Hydro and Suncare Application3Solution Portfolio4Innovation Journey in Sun CareWaterOilOctober 24BMDBMEHMCEHSOCRB3PBSADBTUvinul T 150Tinosorb M 199520002002PS-15Tinosorb S Uvinul A Plus20042006Uvinul A
2、 Plus Granular 20082010Tinosorb S AquaTinosorb A2B20132017Tinosorb S Lite Aqua2022Z-Cote Sheer 2023Tinomax CCUvinul TS HydroA UVA filter in water is introduced2024DPDTOctober 245Water solubleLightweight textureBalanced UVA protectionSustainable/Natural OriginWhy New UVA Filter in Water?Water Soluble
3、A solution when the concerning UV filters are taken outOctober 246Uvinul TS Hydro is water soluble therefore suitable without additional solubilizers It is on-going to reformulate by taking out of concerning UV filters,i.e.EHMC(Uvinul MC 80),octocrylene,etc.Solubility capacities of the oil phase wil
4、l be reduced by taking out of EHMC and octocrylene Not easy to reformulate sunscreens010203040Tinosorb SUvinul T 150Uvinul A PlusSolubilityUvinul MC 80OctocryleneCetiol ABCetiol BCetiol SensoftLightweight TextureClaim evolution in globalOctober 247Fresh/Watery/Lightweight claims are under increasing
5、Evolution of the light claimsLightweight Watery Fresh in the growthNumber of launched sunscreensShare of the sensory claimwhere Sub-Category matches Sun-Sun/Sunbed Exposure and Product Description matches watery or lightweight or fresh with word variantsFrom 2018 to Dec 2023Fresh35%Lightweight53%Wat
6、ery12%Fresh27%Lightweight60%Watery13%201820230%10%20%30%02004006008001,000201820192020202120222023SunscreenShare(%)Balanced Protection for Synergistic UV ProtectionOctober 248Insight on Sunscreen Film by Sunscreen EmulsionLight microscopic pictures of an O/W emulsion containing oil-dispersed Sudan R
7、ed III pigment(CI 26100)and water-dispersed blue pigment(CI42090)Residual areas of the water phase leave skin without UV protection if only lipophilic UV filters are used.During spreadingAfter spreadingBefore spreadingM Sohn,Chaper 13,UV Booster&Photoprotection Extract from Principles and Practice o
8、f Photoprotection,S.Q Wang,H.W LimBalanced Protection for Synergistic UV ProtectionSunscreen efficacyOctober 249Balanced protection in oil and water is key for sunscreen efficacyBalanced Protection in Oil and Water PhaseUnbalanced ProtectionUV Filter Composition(active matter wt%)PerformanceOilUvinu
9、l A Plus(4.0%)TinosorbS(1.5%)UvinulT 150(1.3%)WaterUvinulTS Hydro(4.0%)*TinosorbS Lite Aqua(2.0%)*OilUvinul A Plus(5.8%)TinosorbS(2.3%)UvinulT 150(1.5%)EHS*(3.0%)Water-TinosorbS Lite Aqua(2.2%)*active matter*EHS,ethylhexyl salicylateUV filter total(%)12.8SPFin silico30.0UVA-PFin silico32.4Filter eff
10、iciency(UVA-PF)2.53EcoSun Pass295UV filter total(%)14.8SPFin silico30.1UVA-PFin silico27.4Filter efficiency(UVA-PF)1.85EcoSun Pass0SustainableRelevant with EnvironmentOctober 24101308462524635332919121212976307260Ethical-Environmentally Friendly Package300Brightening/IlluminatingAnti-AgeingVitamin/M
11、ineral FortifiedFragrance FreeFor Sensitive SkinAntioxidantProtects Against ElementsParaben FreeMineral Oil/Petroleum FreeEase of UseDermatologically TestedMoisturising/HydratingWhitening405392Claims 2018-2023 in Sun Care(%of change)INCIEthical-SustainableEthical-RecyclingVegan/No Animal Ingred.Ethi
12、cal Envron.FriendlyNon-comedogenicEthical AnimalOctober 2411Water solubleLightweight textureBalanced UVA protectionSustainable/Natural OriginWhy New UVA Filter in Water?UvinulTS HydroProfiles and Key BenefitsOctober 2412ProfilesINCI nameTerephthalylidene dicamphor sulfonic acid(TDSA)AppearanceClear
13、to yellowish transparent liquidType30-34%aqueous solutionApproved use conc.10%EU,Aus,Mercosur,CN,KR,JPWater solubleAdditional UVA protectionBalanced protection with Uvinul A PlusHigh quality controlPhoto-stableExcellent compatibilityNaturalness90%03006009001200150029030031032033034035036037038039040
14、0E1%/1cmWavelength(nm)Uvinul TS HydroUvinul A PlusKey BenefitsOctober 2413PhotostabilityUvinul TS Hydro*PhotostabilityOctober 2414Uvinul TS Hydro shows good photostabilityCompared to other UVA filtersIn combination with other UV filters0%20%40%60%80%100%05101520Recovery UV FilterUV exposure(MED)TDSA
15、DHHBBMDBMMBBT0%20%40%60%80%100%05101520Recovery TDSAUV exposure(MED)TDSATDSA+DHHBTDSA+EHTTDSA+BEMTTDSA+MBBT*TDSA;Uvinul TS Hydro,DHHB;Uvinul A Plus,BMDBM;Butyl Methoxydibenzoylmethane,MBBT;Tinosorb MUvinul TS Hydro(TDSA)PhotostabilityOctober 2415Uvinul TS Hydro does not generate free radical upon UV
16、 exposure When irradiated photo-isomerisation takes place TDSA works on the principle of reversible photo-isomerization,followed by photo excitation.TDSA absorbs UV light and releases energy in the form of heat without penetration into the skin.Absorbing UV TDSA molecule change from trans-isomer int
17、o cis-isomer.Free radical generation studySampleUV Filter%generated of free radical UV-22-009-7-1Placebo4.3 0.23UV-22-009-7-26%Uvinul TS Hydro+Triethanolamine 4.2 0.23UV-22-009-7-36%Uvinul TS Hydro+Arginine0.3 0.23A.R.Abid et al./Journal of Photochemistry and Photobiology A:Chemistry 332(2017)241250
18、Formation of photo-isomerOctober 2416Performance in formulationUvinul TS HydroPerformance in formulation|oil soluble UV filtersOctober 2417Trade nameINCI%by weightUV-22-009-11-1UV-22-009-11-2UV-22-009-11-4AEumulgin PrismaDisodium Cetearyl Sulfosuccinate1.001.001.00Emulgade PL 68/50Cetearyl Glucoside
19、(and)Cetearyl Alcohol3.003.003.00Lanette OCetearyl Alcohol0.800.800.80Cetiol ABVC12-15 Alkyl Benzoate7.007.007.00Cetiol BDibutyl Adipate15.0015.0015.00Cetiol SensoftPropylheptyl Caprylate5.005.005.00Euxyl PE9010Phenoxyethanol(and)Ethylhexylglycerin1.001.001.00Uvinul T 150Ethylhexyl Triazone3.003.003
20、.00Tinosorb SBis-Ethylhexyloxyphenol Methoxyphenyl Triazine3.503.503.50Uvinul A PlusDiethylamino Hydroxybenzoyl Hexyl Benzoate4.504.504.50BWaterAqua47.9044.3037.10GlycerinGlycerin5.005.005.00Verdessence Xanthan Xanthan Gum0.300.300.30CUvinul TS Hydro Aqua(and)Terephthalylidene Dicamphor Sulfonic Aci
21、d-3.009.00L-ArginineArginine0.601.80DCetiol UltimateUndecane(and)Tridecane3.003.003.00Uvinul TS HydroPerformance in formulation|oil soluble UV filtersOctober 2418Uvinul TS Hydro increases significantly SPF and UVA-PF SPF UVA-PF05101520Formula SPF 25+1%TDSA+3%TDSAUVA-PF in vitro12.714.717.4UVA-PF val
22、ue071421283542Formula SPF 25+1%TDSASPF in silico2529SPF in vivo Inst 12833SPF in vivo Inst 238SPF valueUvinul TS HydroPerformance in formulation|oil soluble+water soluble UV filtersOctober 2419Trade nameINCI%by weightUV-22-009-15-1UV-22-009-15-2AEumulgin PrismaDisodium Cetearyl Sulfosuccinate1.001.0
23、0Emulgade PL 68/50Cetearyl Glucoside(and)Cetearyl Alcohol3.003.00Lanette OCetearyl Alcohol0.800.80Cetiol ABVC12-15 Alkyl Benzoate7.007.00Cetiol BDibutyl Adipate15.0015.00Cetiol SensoftPropylheptyl Caprylate5.005.00Euxyl PE9010Phenoxyethanol(and)Ethylhexylglycerin1.001.00Uvinul T 150Ethylhexyl Triazo
24、ne2.502.50Tinosorb SBis-Ethylhexyloxyphenol Methoxyphenyl Triazine2.002.00Uvinul A PlusDiethylamino Hydroxybenzoyl Hexyl Benzoate3.003.00BWaterAqua47.9044.30GlycerinGlycerin5.005.00Verdessence XanthanXanthan Gum0.300.30CUvinul TS Hydro Aqua(and)Terephthalylidene Dicamphor Sulfonic Acid-3.00L-Arginin
25、eArginine-0.60DPBSAPhenylbenzimidazole Sulfonic Acid1.501.50WaterAqua10.0010.00L-ArginineArginine0.830.83ECetiol UltimateUndecane(and)Tridecane3.003.00Uvinul TS HydroPerformance in formulation|oil soluble+water soluble UV filtersOctober 2420Uvinul TS Hydro increases significantly SPF and UVA-PF SPF
26、UVA-PF071421283542Formula SPF 25+1%TDSASPF in silico25.128.2SPF in vivo29.740.3SPF value051015Formula SPF 25+1%TDSAUVA-PF in vitro9.413.8UVA-PF value+UvinulTS Hydro(3%)+UvinulTS Hydro(3%)Uvinul TS HydroPerformance in formulation|oil soluble+water soluble UV filtersOctober 2421Trade nameINCIUV-DE-23-
27、TD-153-033-1-1UV-DE-23-TD-153-033-1-2AEmulgade Verde 10MSPolyglyceryl-10 stearate3,003,00Cetiol BDibutyl Adipate10,0010,00Cetiol CCDicaprylyl Carbonate10,0010,00Myritol PGDCPropylene Glycol Dicaprylate/Dicaprate6,006,00Euxyl PE 9010Phenoxyethanol,Ethylhexylglycerin1,001,00Uvinul A PlusDiethylamino H
28、ydroxybenzoyl Hexyl Benzoate8,008,00Uvinul T 150Ethylhexyl Triazone4,004,00Tinosorb SBis-Ethylhexyloxyphenol Methoxyphenyl Triazine3,503,50BWaterAqua37,9042,85Hydrasensyl Glucan GreenWater,Pentylene Glycol,Beta-Glucan,Caprylyl Glycol3,003,00Lecithin0,100,10Avicel PC 611Microcrystalline cellulose,Cel
29、lulose gum1,001,00CWaterAqua5,005,00Eusolex 232PBSA1,701,70Trisamino Ultra PCTromethamine0,750,75Uvinul TS HydroTerephthalylidene Dicamphor Sulfonic Acid4,50-Trisamino Ultra PCTromethamine0,55-Citricacid 30%0,10Uvinul TS HydroPerformance in formulation|oil soluble+water soluble UV filtersOctober 242
30、2Uvinul TS Hydro increases significantly SPF and UVA-PF SPF UVA-PF020406080Formula SPF 44+1,5%TDSASPF in silico4449SPF in vitro4475SPF value+UvinulTS Hydro(4,5%)07142128Formula SPF 44+1,5%TDSAUVA-PF in vitro2426UVA-PF value+UvinulTS Hydro(4,5%)October 2423Formulating with Uvinul TS HydroUvinul TS Hy
31、droImpact of neutralizer on sensoryOctober 2424Best neutralizers for sensory are Tromethamine and L-ArginineAlkalineSensory*tested on 10%Uvinul TS Hydro solutions(pH 6.5-7.0)During applicationSemi-dryDryNeutrol TEStrong stop feelingStrong sticky and squeakyStrong sticky and squeakyTromethamineMedium
32、 stop felling in the endMedium sticky and squeakySlight sticky and squeakyTriethanolamine TEAMedium stop felling in the endStrong sticky,medium squeakyMedium sticky and squeakyL-ArginineStrong stop feelingStrong sticky and squeakyVery slight sticky and squeakyVery quick transition*First sensory impr
33、ession by only one experienced panelUvinul TS Hydro Impact of neutralizer on noodling effectOctober 2425Tromethamine looks to be the best suitable neutralizer to avoid noodling effectNeutrol TEUV-CN-23-CY041401TriethanolamineUV-CN-23-CY041402ArginineUV-CN-23-CY041403TromethamineUV-CN-23-CY030201Test
34、 protocolWeighted 0.15g of the formulation and applied onto back of the handDrew 20 circles on the back of the hand with the index and middle fingers to distribute the product evenly Removed any excess product from the finger and wait for 1min After 1min,drew 30 more circles by the index and middle
35、finger to observe the noodling October 2426Naturalness and SustainabilityUvinulTS HydroOrigins and Natural MoietyOctober 2427Camphor treeUvinulTS HydroNaturalness and SustainabilityOctober 242890%Natural Origin71%Renewable Carbon ContentOctober 2429Application example3025.10.2024|Additional informat
36、ion30|Balanced protection fluid|Bi-phase sprayInvisible October 2434We care:for our customers,consumers,employees,societyand our planet.We strive:for sustainable contributions for example in the areasof renewables,responsible sourcing and carbon footprintreduction.We innovate:to drive transformation
37、 to ecologically compatiblesolutions.Already today:we are leading in our markets offering one of thebroadest portfolios in terms of sustainability for the personal care,homecare and industrial&institutional(I&I)care and industrial formulators industries.Benefit for you:new seamless digital customer
38、experience withimproved ease-of-doing business and cutting-edge digital services.Uvinulis just one recent example of how BASFs Care Chemicals Division is addressing future challenges in sustainability,digitalization,innovation and new approaches to working together.This document,or any answers or in
39、formation provided herein by BASF,does not constitute a legally binding obligation of BASF.While the descriptions,designs,data and information contained herein are presented in good faith and believed to be accurate,it is provided for your guidance only.Because many factors may affect processing or
40、application/use,we recommend that you make tests to determine the suitability of a product for your particular purpose prior to use.It does not relieve our customers from the obligation to perform a full inspection of the products upon delivery or any other obligation.NO WARRANTIES OF ANY KIND,EITHE
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